Development of New Synthetic Pathways for Renewable Energy Storage
DOI:
https://doi.org/10.70749/ijbr.v3i1.615Keywords:
Renewable Energy Storage, Synthetic Pathways, Green Chemistry, Lithium-ion Batteries, Supercapacitors, Hydrogen Storage, Metal-organic Frameworks (MOFs)Abstract
Due to the intermittent nature of renewable energy sources (solar, wind), there is a need to develop efficient, scalable, and sustainable energy storage systems. Existing energy storage technologies face fundamental challenges, and this study aimed to tackle those challenges by exploring new synthetic routes for novel materials. It focused on enhancing the performance, scalability, and environmental sustainability of energy storage technologies, including lithium-ion batteries, supercapacitors, and hydrogen storage systems. Designing metal-organic frameworks (MOFs), perovskites and polymer electrolytes via green chemistry principles to minimize the environmental impact of produced materials. The cyclic voltammetric, electrochemical impedance spectroscopic and long-term cycle stability measurements of electrochemical performance were conducted. Density Functional Theory (DFT) simulations for computational modelling were used to predict material properties and optimize reaction pathways. In these results, MOF based Lithium-ion batteries achieved the best energy density (310 Wh/kg); polymer based supercapacitors exhibited high power density (2000 W/kg) and cycling stability (94% retention after 1000 cycles). Recently stability of perovskite-based hydrogen storage systems was improved to 88% of the capacity after 1000 cycles. The results confirmed that using high-performance materials from 21st century fibres with sustainable synthesis approaches solved key performance and sustainability challenges. It lays a foundation towards stackable and sustainable energy storage systems, which can be used in technological energy grids, electric vehicles, and portable devices.
Downloads
References
Al Rai, A., & Yanilmaz, M. (2021). High-performance nanostructured bio-based carbon electrodes for energy storage applications. Cellulose, 28(9), 5169-5218. https://doi.org/10.1007/s10570-021-03881-z
Cao, F., Zhao, M., Yu, Y., Chen, B., Huang, Y., Yang, J., Cao, X., Lu, Q., Zhang, X., Zhang, Z., Tan, C., & Zhang, H. (2016). Synthesis of two-dimensional CoS1. 097/nitrogen-doped carbon nanocomposites using metal–organic framework nanosheets as precursors for supercapacitor application. Journal of the American Chemical Society, 138(22), 6924-6927. https://doi.org/10.1021/jacs.6b02540
Cheng, X., Zhao, M., Chen, C., Pentecost, A., Maleski, K., Mathis, T., Zhang, X., Zhang, Q., Jiang, J., & Gogotsi, Y. (2017). Nanodiamonds suppress the growth of lithium dendrites. Nature Communications, 8(1). https://doi.org/10.1038/s41467-017-00519-2
Dong, Y., Wang, B., Zhao, K., Yu, Y., Wang, X., Mai, L., & Jin, S. (2017). Air-stable porous Fe2N encapsulated in carbon microboxes with high volumetric lithium storage capacity and a long cycle life. Nano Letters, 17(9), 5740-5746. https://pubs.acs.org/doi/abs/10.1021/acs.nanolett.7b02698
Hamers, R. J. (2020). Energy storage materials as emerging nano-contaminants. Chemical Research in Toxicology, 33(5), 1074-1081. https://doi.org/10.1021/acs.chemrestox.0c00080
Indra, A., Song, T., & Paik, U. (2018). Metal organic framework derived materials: Progress and prospects for the energy conversion and storage. Advanced Materials, 30(39). https://doi.org/10.1002/adma.201705146
Liu, T., Kavian, R., Chen, Z., Cruz, S. S., Noda, S., & Lee, S. W. (2016). Biomass-derived carbonaceous positive electrodes for sustainable lithium-ion storage. Nanoscale, 8(6), 3671-3677. https://doi.org/10.1039/c5nr07064c
Ma, Q., Yu, Y., Sindoro, M., Fane, A. G., Wang, R., & Zhang, H. (2017). Carbon‐based functional materials derived from waste for water remediation and energy storage. Advanced Materials, 29(13). https://doi.org/10.1002/adma.201605361
Mo, R., Rooney, D., Sun, K., & Yang, H. Y. (2017). 3D nitrogen-doped graphene foam with encapsulated germanium/nitrogen-doped graphene yolk-shell nanoarchitecture for high-performance flexible Li-ion battery. Nature Communications, 8(1). https://doi.org/10.1038/ncomms13949
Nagarajan, D., Dong, C., Chen, C., Lee, D., & Chang, J. (2021). Biohydrogen production from microalgae—Major bottlenecks and future research perspectives. Biotechnology Journal, 16(5). https://doi.org/10.1002/biot.202000124
Niu, S., Wang, Z., Yu, M., Yu, M., Xiu, L., Wang, S., Wu, X., & Qiu, J. (2018). Mxene-based electrode with enhanced Pseudocapacitance and volumetric capacity for power-type and ultra-long life lithium storage. ACS Nano, 12(4), 3928-3937. https://doi.org/10.1021/acsnano.8b01459
Shanbhag, S., Bootwala, Y., Whitacre, J. F., & Mauter, M. S. (2017). Ion transport and competition effects on NaTi2 (PO4) 3 and Na4Mn9O18 selective insertion electrode performance. Langmuir, 33(44), 12580-12591. https://pubs.acs.org/doi/abs/10.1021/acs.langmuir.7b02861
Sun, Q., Dai, Y., Ma, Y., Jing, T., Wei, W., & Huang, B. (2016). Ab initio prediction and characterization of Mo2C monolayer as anodes for lithium-ion and sodium-ion batteries. The Journal of Physical Chemistry Letters, 7(6), 937-943. https://doi.org/10.1021/acs.jpclett.6b00171
Wang, J., Wang, J., Kong, Z., Lv, K., Teng, C., & Zhu, Y. (2017). Conducting‐polymer‐Based materials for electrochemical energy conversion and storage. Advanced Materials, 29(45). https://doi.org/10.1002/adma.201703044
Yabuuchi, N. (2018). Material design concept of lithium‐excess electrode materials with rocksalt‐related structures for rechargeable non‐aqueous batteries. The Chemical Record, 19(4), 690-707. https://doi.org/10.1002/tcr.201800089
Ye, H., Ma, L., Zhou, Y., Wang, L., Han, N., Zhao, F., Deng, J., Wu, T., Li, Y., & Lu, J. (2017). Amorphous MoS3 as the sulfur-equivalent cathode material for room-temperature Li–S and Na–S batteries. Proceedings of the National Academy of Sciences, 114(50), 13091-13096. https://doi.org/10.1073/pnas.1711917114
Zhang, Y., Zhang, L., Lv, T., Chu, P. K., & Huo, K. (2020). Two‐dimensional transition metal Chalcogenides for alkali metal ions storage. ChemSusChem, 13(6), 1114-1154. https://doi.org/10.1002/cssc.201903245
Zhu, B., Liang, Z., & Zou, R. (2020). Designing advanced catalysts for energy conversion based on urea oxidation reaction. Small, 16(7). https://doi.org/10.1002/smll.201906133
Downloads
Published
Issue
Section
License
Copyright (c) 2025 Indus Journal of Bioscience Research

This work is licensed under a Creative Commons Attribution 4.0 International License.